Intermolecular interactions-Oxides

Grigory Seguru
Moscow Power Engineering Institute (MPEI), Moscow, Russia

Valery Fertikov
All-Russia Institute of Light Alloys (JSC “VILS”), Moscow, Russia

  • Keywords:
  • Chemistry, Intermolecular interactions, Two-component oxide systems
  • Abstract:
  • The book presents the results of calculations of the interaction between oxide molecules by comparing the volumes of the components before and after the interaction. The volumes of atoms and molecules are formed by electrons and are dynamic characteristics. Calculations reflect interactions in two-component oxide systems and three-component ones. The packing factor is used as an indicator of interaction. As structural characteristics of substances, it is proposed to describe the space occupied by a substance in terms of the concentration of electrons and the concentration of nucleons. The packing factor characterizes the intensity of the interaction of molecules. Comparison of the electron concentration for different substances makes it possible to predict the physical and mechanical properties of the resulting materials. The book can be considered as a reference book intended for a wide range of physicists, chemists, mineralogists and materials scientists; it can be useful for students of relevant specialties. The presentation is available for high school students.
  • This book is a continuation and extension of the book "Interatomic interactions in the structures of intermetallic compounds."[1]. During chemical interactions (interatomic and intermolecular), both thermal effects and changes in the volumes of the participants in the interactions are observed. As a result of interactions, the combined volume is not equal to the sum of the volumes of the participants in the interaction.
  • Interaction is a mutual action that cannot be separated from the characteristics of the objects involved in the process. Interaction is a process that is characterized by a simultaneous mutual change in the characteristics of interacting material objects. These material objects (atoms or molecules) influence each other with different intensity, obeying certain laws, and reproduce new structures with high accuracy. Chemical bonding is a consequence of both interatomic and intermolecular interactions.
  • Reproductive structures indicate the presence of constitutional characteristics of interacting objects. One of these characteristics is the mass concentrated in the nucleons, and the second is the volume formed by the electron clouds around the nucleons. During chemical interactions, the mass concentrated in nucleons remains unchanged, while the resulting volume changes, decreasing or increasing. The volume of electronic clouds is a dynamic characteristic. The electron cloud changes its volume and shape depending on external influences (pressure and temperature). Such an external influence is the environment of a particular type of atoms with atoms of a different type. From the relative change in volume, as well as from thermal effects, one can judge the intensity of the interaction.
  1. G. Seguru, V. Fertikov. Interatomic Interactions in the Structures of Intermetallic Compounds. 2021, Society for Science and Education (United Kingdom) DOI: 10.14738/eb.207.2021
  2. P. Glensdorf, I. Prigozhin. The thermodynamic Theory of Structure, Stability and Fluctuations, translation from English, under editorship of Y. A. Chizmodzev, Moscow, Editorial URSS (2003) (in Russian).
  3. B. N. Arzamasov, V. I. Makarova, G. G. Mukhin, N. M. Ryzhov, V. I. Silaev. Materialovedenie, Moscow, MGTU n.a. N. E.Bauman Publ. (2005). (in Russian).
  4. Ya.A. Ugay, General and Inorganic Chemistry. Мoscow: Higher school, 1997. 527 pages.
  5. Meyer J.L., Die Naturder Chemischen Elemente als Function ihrer Atomgewichte, “Annalen der Chemie und Pharmacie”, 1870, Bd 7 (Suppl.), S. 354-64.
  6. N.V. Molchan, V.I. Fertikov, Density of Substances as a Result of Interacting of Their Components // Technology of Low-Density Alloys. – 2009. – No. 1, P. 22-29. (in Russian).
  7. N.V. Molchan, V.I. Fertikov, A method of Estimation of Reactivity of Hydrogen, Boron, Carbon, and Nitrogen // Technology of Low-Density Alloys. – 2009. – No. 2, P. 47-56. (in Russian).
  8. Handbook of Physical Constants. Sydney P. Clark, Published by the Society, 1966.
  9. Physical Chemistry / Edited by Academician B.P. Nikolsky. Leningrad: Chemistry, 1997. 880 pages. (in Russian).
  10. N.V. Molchan, V.I. Fertikov, Electron Density and Mechanical Characteristics of Substances // Materials of conference “TestMat-2013”, Moscow, FSUE “VIAM”, 28 February – 1 March 2013, stand re-port. .(in Russian).
  11. A.P. Babichev, N.A. Babushkina, A.M. Bratkovsky et al. Physical Quantities // Reference book edited by I.S. Grigoriev, E.Z.Mejlihova. Мoscow: Energoatomizdat, 1991. 1232 pages. (in Russian).
  12. International Centre for Diffraction Data. JCPDS PCPDFWIN. 2002. – V.2.03.
  13. Novyy spravochnik khimika i tekhnologa. Osnovnye svoystva neorganicheskikh, organicheskikh I elementoorganicheskikh soedineniy [The new reference book for chemist and technologist. The basic properties of inorganic, organic and element organic compounds]. St.-Petersburg: Professional, 2007, 1276 p (in Russian).
  14. D.I. Mendeleev Compositions. Volume 04. Solutions. Edited by V.E. Tishchenko. (Leningrad: ONTI. Khimteoret, 1937) p (in Russian).
  15. Molchan N., Krivoborodov Yu., Fertikov V. The interaction of water with oxides, forming hydroxides and crystal hydrates, //Technique and technology of silicates, 2017; 1: 11-15. (in Russian)
  16. Molchan N., Krivoborodov Yu., Fertikov V.Intermolecular interactions in two-component oxide systems with SiO2. //Technique and technology of silicates, 2018; v.25;3 80-84. (in Russian)
  17. Molchan N., Krivoborodov Yu., Fertikov V. Intermolecular interactions in two-component oxide systems with CaO. //Technique and technology of silicates, 2019. – V. 26, 1. 25–29. (in Russian).
  18. Seguru, G., Fertikov, V. (2021). Intermolecular Interactions in Spinel Structures. //European Journal of Applied Sciences, 9(3). 568-576.
  19. Sigaev V.N., Sarkisov P.D., Datsenko A.M., Fertikov V.I., Pozhogin O.A., Zakharkin D.A., Pernice P., Aronne A., Stefanovich S.Yu. SURFACE AND BULK STILLWELLITE TEXTURES IN GLASSES OF THE La2 O3-B2O3-GeO2 SYSTEM Journal of the European Ceramic Society. 2004. Т. 24. № 6. С. 1063-1067.
  20. Sigaev V.N., Sarkisov P.D., Kim T.V., Fertikov V.I., Avdyushin K.N., Stefanovich S.Yu., Mosunov A.V., Pernice P., Aronne A., Parfenov B.G., Segalla A.G FERROELECTRIC COMPOSITES AND CERAMICS BASED ON STILLWELLITE-LIKE SOLID SOLUTIONS. Journal of the European Ceramic Society. 2004. Т. 24. № 6. С. 1569-1572.
  21. Molchan N., Krivoborodov Yu., Fertikov V. The interaction of water with oxides, forming hydroxides and crystal hydrates, //Technique and technology of silicates, 2017; 1: 11-15. (in Russian)
  22. Molchan N., Krivoborodov Yu., Fertikov V.Intermolecular interactions in two-component oxide systems with SiO2. //Technique and technology of silicates, 2018; v.25;3 80-84. (in Russian)
  23. Molchan N., Krivoborodov Yu., Fertikov V. Intermolecular interactions in two-component oxide systems with CaO. //Technique and technology of silicates, 2019. – V. 26, 1. 25–29. (in Russian).
  24. Seguru, G., Fertikov, V. (2021). Intermolecular Interactions in Spinel Structures. //European Journal of Applied Sciences, 9(3). 568-576.
  25. 25. N.V. Molchan, V.I. Fertikov, Compressibility of Substances and Dimensions of Atoms // – 2011. – No. 6, P. 2-6. (in Russian).
  26. P. Bridgman The Physics of High Pressure. New York: Macmillan Co., 1931
  27. Seguru G., Fertikov V. Interaction of Elements in Binary Compounds of Hydrogen// American Journal of Chemistry and Application. – 2017. – Vol. 4,№ 6. – P. 59–62.
  28. Molchan N. V., Fertikov V. I. Interrelation of Thermodynamic Parameters and Structural Characteristics, with Halidesof Groups 1 and 2 Elements as an Example. //American Journal of Chemistry and Application, 2016, vol. 3, no. 5, pp. 28–32.
  29. N. V. Molchan, G.V.Seguru, V. I. Fertikov. A Method of Magnesium Alloy Structure Control, Patent RF 2558632 (2015)
  30. Molchan N. V., Fertikov V. I. Interrelation of Thermodynamic Parameters and Structural Characteristics, with Halidesof Groups 1 and 2 Elements as an Example. //American Journal of Chemistry and Application, 2016, vol. 3, no. 5, pp. 28–32.
  31. N. V. Molchan, G.V.Seguru, V. I. Fertikov. A Method of Magnesium Alloy Structure Control, Patent RF 2558632 (2015)
  32. Molchan N., Krivoborodov Yu., Fertikov V. Intermolecular interactions in two-component oxide systems with CaO. //Technique and technology of silicates, 2018; 4: 106-109. (in Russian)
  33. N. V. Molchan, V. I. Fertikov. A Method of Titanium Alloy Structure Control, Patent RF 2486494 (2013)
  34. N. Molchan, I. Polkin, V. Fertikov, Ability to Control a Titanium-alloy Structure by Atomic-Emission Spectroscopy // Journal of Applied Spectroscopy 2 (2014) 169-173. (in Russian).
  35. N. V. Molchan, V. I. Fertikov. A Method of Steel Structure Control, Patent RF 2518292 (2014)
  36. N.V. Molchan, V.I. Fertikov Control of steel structure changes during annealing by atomic emission spectroscopy. //Zavodskaya Laboratoriya, Diagnostika materialov. -2016, V .82, no. 5, pp. 39 – 43.
  37. Fertikov V., Seguru G. The Interaction of Iron with the Chemical Elements, Forming Binary Compounds //  SciFed Journal of Metallurgical Science – 2017. – V.1.Iss.I. P.1 -5.   
  38. 37. V. Molchan, D. S. Eliseev, G.V. Seguru, V. I. Fertikov. A Method of Nickel Alloy Structure Control, Patent RF 2581077 (2016)
  39. Molchan N., Eliseev D., Fertikov V. Control of Nickel Alloy Structural Change by the Atomic Emission SpectroscopyMethod // American Journal of Analytical Chemistry. – 2016. – Vol. 7, № 9. – P. 633–641.
  40. Fertikov V., Seguru G. Assessment of Changes in Volume of Nickel Compounds Interacting With the Chemical Elements // International Journal of Current Research. – 2017 .- V.9, Iss. 08. P.56361-56364.
  41. N. V. Molchan, V. I. Fertikov. A Method of Brass Structure Control, Patent RF 2531339 (2014)
  42. N. V. Molchan, V. I. Fertikov. A Method of Aluminum Alloy Structure Control, Patent RF 2442139 (2012)
  43. N.V. Molchan, V.I. Fertikov. Metals, No.3 (2012) 84-87
  44. N.V. Molchan, V.Yu Konkevich V.Yu, V.I. Fertikov. Control of structural changes in aluminum alloy 1379p, obtained by granular technology, by atomic emission spectroscopy. //Zavodskaya  Laboratoriya, Diagnostika materialov. -2017.  V. 83. no. 2, pp .42-45.
  45. N.V. Molchan, V.I. Fertikov. Application of atomic emission spectroscopy to control the structure of aluminum alloy. // Materials of conference “TestMat-2013”, Moscow, FSUE “VIAM”, 28 February – 1 March 2013, stand re-port. (in Russian).
  46. Molchan N., Krivoborodov Yu., Fertikov V. Interatomic interactions in binary aluminum compounds. //Technique and technology of silicates, 2019; 3: 82-85. (in Russian)
  47. Molchan N., Krivoborodov Yu., Fertikov V. The interaction of silicon with the chemical elements, forming with it a binary connection. //Technique and technology of silicates, 2017; 4:11-17. (in Russian)
  48. Seguru G., Fertikov V. Interatomic Interactions in Binary Nitrogen Compounds // International Journal of Innovation in Engineering Research & Management. – 2018 – V. 05. Iss. 02. P. 1-5.
  49. Molchan N.V., Fertikov V.I. Concentration of electrons as a structural characteristic of oxides ]. Tekhnika I tekhnologiya silikatov, 2016, vol. 23, no. 2, pp. 8–13 (in Russian).
  50. Nina V. Molchan, Valery I. Fertikov Determination of Concentration of Electrons for Descrition of the Structure of Materials, with Sulfides as an Example. //Journal of Materials Sciences ad Applications. Vol. 1, No. 2, 2015, pp. 38-44.
  51. Seguru G., Fertikov V. (2021). Interatomic Interactions in Binary Plutonium Compounds. . //European Journal of Applied Sciences, 9(4). 85-93.
PDF
Published
  • September 15, 2022
Categories
Copyright
  • Copyright (c) 2022 Grigory Seguru & Valery Fertikov
License

This work is licensed under a Creative Commons Attribution 4.0 International License.