Study of Excess Volumetric and Thermodynamic Properties and Viscosity Modeling for Binary Liquid Mixtures of Isopropyl Benzene (cumene) with Aromatic Hydrocarbons at Temperature 298.15 K and Under Atmospheric Pressure
DOI:
https://doi.org/10.14738/aivp.1306.19780Keywords:
density, Speed of sound, \viscosity, excess properties, excess free volume, excess internal pressure, cumene, binary system, aromatic hydrocarbonsAbstract
The present discussion embodies the studies on binary mixtures containing isopropyl benzene (cumene) + ethyl benzene, isopropyl benzene (cumene) + toluene, isopropyl benzene (cumene) + mesitylene, isopropyl benzene (cumene) + n-propyl benzene, isopropyl benzene (cumene) + tert-butyl benzene, and isopropyl benzene (cumene) + biphenyl at the 298.15 K. For this purpose, the density, viscosity and speed of sound for pure liquids and their binary mixtures were measured within the temperature range 298.15K. Various excess and deviation parameters have been calculated using the measured properties. These properties provide valuable insight into molecular interactions and help predict the behaviour of complex chemical systems. Excess and deviation parameters were fitted to the Redlich−Kister polynomial.
References
Das, N.; Praharaj, M. K.; Panda, S. Exploring ultrasonic wave transmission in liquids and liquid mixtures: A comprehensive overview. J. Mol. Liq. 2024, 403, No. 124841.
Rathnam, M. V.; Ambavadekar, D. R.; Nandini, M. Densities, viscosities, and sound speed of binary mixtures of hexyl acetates with tetrahydofuran, 1, 4-dioxane, anisole, and butyl vinyl ether. J. Chem. Eng. Data 2013, 58, 3370−3377.
Vanathi, V.; Mullainathan, S.; Nithiyanantham, S. PhysioChemical Studies on the Ternary Mixture of Chlorobenzene +Chloroform+Cyclohexane Liquid Mixtures at 303.15, 308.15 and 313.15 K. J. Comput. Theor. Nanosci. 2013, 10, 1952−1955.
Varma, R. P.; Kumar, S. Ultrasonic velocity and density measurements of ammonium soaps in 2-propanol. Indian J. Pure Appl. Phys. 2000, 2, 96−100.
Tironi, I. G.; Wilfred, F. V. G. A molecular dynamics simulation study of chloroform. Mol. Phys. 1994, 83, 381−403.
Bertagnolli, H.; Leicht, D. O.; Zeidler, M. D. X-ray diffraction study of liquid chloroform. Mol. Phys. 1978, 35, 193−197. (6) Ali, A.; Tiwari, K.; Nain, A. K.; Chakravarty, V. Ultrasonic study of molecular interactions in ternary mixtures of dimethyl sulfoxide (1) + carbon tetrachloride (2) + aromatic hydrocarbons (3) at 308.15 K. Ind. J. Phys. 2000, 74B, 351−355.
Upadhyay, S. K. Ultrasonic study of molecular interactions and compressibility behaviour of lithium soaps in 50:50% (v/v) benzenemethanol mixture. Indian J. Chem. 2000, 39A, 537−540.
Ali, A.; Tiwari, K.; Nain, A. K.; Chakravarty, V. Ultrasonic study of molecular interactions in ternary mixtures of dimethyl sulfoxide (1) + carbon tetrachloride (2) + aromatic hydrocarbons (3) at 308.15 K. Ind. J. Phys. 2000, 74B, 351−355.
J. George, N.V. Sastry, J. Chem. Eng. Data 48 (2003) 1529–1539.
E. Zorebski, M. Dzida, M. Piotrowska, J. Chem. Eng. Data 53 (2008) 136–144.
T. Katrinˇák, L. Hnedkovsky´ , I. Cibulka, J. Chem. Eng. Data 57 (2012) 1152–1159.
C. Lisa, M. Ungureanu, P.C. Cosmat¸chi, G. Bolat, The density, the refractive index and the adjustment of the excess thermodynamic properties by means of the multiple linear regression method for the ternary system ethylbenzene–octane–propylbenzene, Thermo chim. Acta, 617 (2015) 76–82. https://www.sciencedirect.com/journal/thermochimica-acta/vol/617/suppl/C
D. D. Perrin, W. L. F. Armarego, purification of Laboratory Chemicals 3rdEdn. (Pergamon, UK) (1988). https://www.scirp.org/reference/referencespapers?referenceid=1287461
Y. Zhao, J. wang, X. Xuan, J. Lu, “Effect of Temperature on Excess Molar Volumes and Viscosities for Propylene Carbonate + N,N-Dimethylformamide Mixtures” J Chem. Eng. Data, 45(3) (2000) 440-444. https://pubs.acs.org/doi/10.1021/je9902746
E. Hanan, M. El-sayed, A. Abdul-Fattah, Asfour. Density and viscosity of the regular quinary system: Benzene (1) + Toluene (2) + Ethyl benzene (3) + Heptane (4) + Cyclooctane (5) and its quaternary subsystems at 293.15 and 298.15K. J. Solution Chem. 42(2013) 136-150. https://link.springer.com/article/10.1007/s10953-012-9950-0
V. K. Rattan, S. Singh, B.P.S. Sethi, Viscosity, density and Ultrasonic velocities of binary mixtures of Ethylbenzene with ethanol, 1-propanol and 1-butanol at (298.15 and 308.15) K. J. Chem. Engg. Data, 49(4) (2004)1074- 1077. https://pubs.acs.org/doi/10.1021/je049912x
J. A. Riddick, W.B. Bunger, T. K. Sakano, Organic solvents: Physical properties and Methods of Purification, th 4 ed.: Willey Interscience. New York, (1986). https://www.scirp.org/reference/referencespapers?referenceid=2259333https://www.osti.gov/biblio/6190969
Thermodynamic Research Center, Texas A & M University, College Station, T RC Thermodynamic Tables Hydrocarbons, Suppl. No. 92 (1988). https://books.google.co.in/books/about/TRC_Thermodynamic_Tables.html?id=vClCAQAAIAAJ&redir_esc=y
A.K. Nain, D. Chand, Correlation between molecular interactions and excess thermodynamic parameters of binary mixtures. J. Pure Appl. Ultrason. 43(2021) 8-16. https://docs.google.com/gview?url=http://www.ultrasonicsindia.org/USI-43(1-2)2021.pdf&embedded=true
M.I. Aralaguppi, T.M. Aminabhavi, S.B. Harogoppad, R.H. balindgi, J. Chem. Eng. Data, 37(3) (1992) 29-303. https://pubs.acs.org/doi/pdf/10.1021/je00007a006
B.K. Sarkar, A. Choudhury, B. Sinha, Excess molar volume, excess viscosities and ultrasonic speed of sound of binary mixtures of 1,2-Dimethoxyethane with some aromatic liquids at 298.15K. J. Solution Chem., 41(2012) 53-74. https://link.springer.com/article/10.1007/s10953-011-9780-5
A.K. Nain, Ultrasonic and viscometric studies of molecular interactions in binary mixtures of tetrahydrofuran with some aromatic hydrocarbons at temperatures from 288.15 to 318.145K. Physics and Chemistry of Liquids. 45(4) (2007) 371-388. https://doi.org/10.1080/00319100701230405
J. M. Resa, C. Gonzalez, S. Prieto, E. Diez, M. Iglesias, Mixing properties of propyl acetate + aromatic hydrocarbons at 298.15K. Korean J. Chem. Eng. 23(1) (2006) 93-101. https://link.springer.com/article/10.1007/BF02705698
TRC thermodynamic tables, Thermodynamic Research Center, Texas A & M University, College Station, TX (1994). https://link.springer.com/chapter/10.1007/978-3-642-74140-1_6
J. M. Resa, C. Gonzalez, de L. Ortiz, J. Lanz, Densities, excess molar volume and refractive indices of ethyl acetate and aromatic hydrocarbon binary mixtures. J. Chem. Thermodyn., 34 (7) (2002) 995-1004.
D. K. Sharma, C. P. Prajapati, S. Kumar, Density, Ultrasonic Velocity, Viscosity and their Excess Parameters of Some Binary Liquid Mixtures of Cumene with Aromatic Hydrocarbons at 298.15 K. Der Pharma Chemica.16(2) (2024) 301-306. https://www.derpharmachemica.com/archive/dpc-volume-16-issue-2-year-2024.html
M. A. Saleh, M. Habibullah, M. Shamsuddin Ahmed, M. Ashraf Uddin, S. M. H. Uddin, M. Afsar Uddin & F. M. Khan, Excess molar volume and viscosities of some alkanols with Cumene. Physics and Chemistry of liquids, 44(1) (2006) 31- 43. https://doi.org/10.1080/00319100500287853https://www.tandfonline.com/toc/gpch20/44/1?nav=tocList
S. Aktar, M. Abdur Rahman, M. Shahadat Hossian, S. Akhtar, Excess molar volume and deviation in viscosity of the binary liquid mixtures of 1-Pentanol + Aromatic Hydrocarbons at 298.15K. European Scientific Journal. 11(5) (2015) 213-225. https://eujournal.org/index.php/esj.
M. Page, J. Huot, A. Jolicoeur, Comprehensive thermodynamic investigation of water-ethanolamine mixtures at 10, 25 and 40 0C. Can. J. Chem., 45(1993) 1064-1072. https://www.sciencedirect.com/org/journal/canadian-journal-of-chemistry/issues
N. G. Tsierkezos, M. M. Palaiologou, I E. Molinou, Densities and Viscosities of 1-Pentanol binary mixtures at 293.15K. J. Chem. Eng. Data. 45(2000) 272-275. https://pubs.acs.org/doi/10.1021/je9902138
M. Kumar, V.K. Rattan, Thermophysical properties for binary mixture of Di methyl sulfoxide and isopropyl benzene at various temperatures. Journal of Thermodynamics, 23 (2013), https://onlinelibrary.wiley.com/journal/6962
M. K. Hossani, A. Rahman, S. Akhatar, Molar Interactions of Some Aromatic Hydrocarbons in n-Heptane by Viscometric Measurements at 298.15K, The Chittagong Univ. J. Sci. 40 (2018) 97-110. DOI: 10.3329/cujs.v40i1.47918
Sh. Fujii, K. Tamura, S. Murakam, Thermodynamic properties of (an alkylbenzene+ cyclohexane) at the temperature 298.15 K. J Chem. Thermodynamics 27(12)(1995) 1319–28. https://www.sciencedirect.com/science/article/pii/S0021961485701401
D.L. Prak, S.L. Graft, Th.R. Johnson, J.S. Cowart, P. C. Trulove, Binary mixtures of aromatic compounds (n-Propylbenzene, 1, 3, 5-trimethylbenzene, and 1, 2, 4-trimethylbenzene) with 2, 2, 4, 6, 6-pentamethylheptane: densities, viscosities, speeds of sound, bulk moduli, surface tensions, and flash points at 0.1 MPa. J. Chem. Eng. Data, 65(5)(2020) 2625-2641. https://pubs.acs.org/toc/jceaax/65/5
R. Padmanaban, A. Gayathri, S. Kapoor, G. A. Iyengar, Dong-Eun Lee, V. Kannan, V. Karthikeyan, D. S. Assi, A.L. Vellaisamy Roy, Comparative Evaluation of Thermophysical and Acoustical Properties of Binary Mixtures of Cumene + Methyl Acetate and Cumene + Ethyl Acetate over the Range of Molar Compositions and Temperatures from 298.15 to 318.15 K: Experimental Measurements and Application of Deviation Modeling. J. Chem. Eng. Data. 70 (2025) 3491−3508. https://pubs.acs.org/toc/jceaax/70/9
D S. Wankhede, Isentropic Compressibility for Binary Mixtures of Propylene Carbonate with Benzene and Substituted Benzene. Journal of the Korean Chemical Society. 56(1) (2012) 7-13. https://www.scimagojr.com/journalsearch.php?q=4700152644&tip=sid&clean=0
S. C. Bhatia, R. Ruman, R. Bhatia, Viscosities, densities, speeds of sound and refractive indices of binary mixtures of o-xylene, m-xylene, p-xylene, ethylbenzene and mesitylene with 1-decanol at 298.15 and 308.15 K. Journal of Molecular Liquids. 159 (3) (2011) 132–141. https://www.sciencedirect.com/journal/journal-of-molecular-liquids/vol/159/issue/3
O. Redlich, A.T. Kister, Algebraic representation of thermodynamic properties and the classification of solutions, Ind. Eng. Chem. 40 (1948) 345–348, https://doi. org/10.1021/ie50458a036
E. C. Bingham, Fluidity and Plasticity, McGraw Hill, New York, (1922).
D.B. Macleod, “On a direct calculation of the viscosity of a liquid, both under ordinary pressures and high pressures, from the viscosity of its vapour, on the basis of a new equation of state”, Trans Faraday Soc., 41, 771-777, (1945). URL: http://dx.doi.org/10.14738/aivp.1306.19780 351
C.V. Suryanarayana and J. Kuppusami, J. Acoust. Soc. Ind. 4, 75 (1976).
C.V. Suryanarayana, Ind. J. Pure Appl. Phys. 27, 751 (1989).
J.H. Hildebrand, R.L. Scott, Regular Solutions (Prentice Hall, Englewood Cliffs, New Jersey, 1962).
Chhikara Y, Yadav JS, Sharma D, Sharma VK. Excess molar volumes, excess molar enthalpies, and excess isentropic compressibilities of binary mixtures containing n-methyl-2-pyrrolidone and isomeric xylenes at 308.15 K. Journal of Solution Chemistry. 2012; 41(10):1696- 1712
A. J. Treszczanowicz, O. Kiyohara, G. C. Benson, J. Chem.Thermodynamics, 253 (1981).
T. M. Aminabhavi, M. I. Aralaguppi, S. B. Harpogoppad and R. H. Bulundgi, J. Chem. Eng Data, 38, 31(1993).
J.M. Resa, C. Gonzalez, J. Lanz, J. A. Mtz. de Ilarduya, “Excess volumes for binary mixtures formed by methyl acetate with aromatic hydrocarbons,” J. of Thermal Anal. and Calorimetry, 52(3) (1998) 895 . https://kchem.org/journal/jkcs.
J. M. Resa, C. Gonzalez, J. Lanz, J. A. Mtz. de Ilarduya, M. Iglesias, “Excess volumes of binary mixtures of vinyl acetate and aromatic hydrocarbons,” J. Chem. Thermodyn., 33(7) (2001) 723-732.
H. Nakayama, K. Shinoda, Enthalpies of mixing of water with some cyclic and linear ethers. J. Chem. Thermodynamics 3(3) (1971) 401-405. https://www.sciencedirect.com/science/article/abs/pii/S0021961471800575
J.M. Resa, C. Gonzalez, R.G. Concha, M. Iglesias Influence of temperature on excess molar volumes for butyl acetate + aromatic hydrocarbons. Phy. Chem. Liq. 42 (5) (2004) 493-520. https://doi.org/10.1080/00319100410001724557
C. Yang, P. Ma Q. Zhou, Excess molar volumes and viscosities of binary mixtures of sulfolane with benzene, toluene, ethylbenzene, p-xylene, o-xylene, and m-xylene at 303.15 and 323.15 K and atmospheric pressure, J. Chem. Eng. Data, 49(4) (2004) 881-885. https://pubs.acs.org/toc/jceaax/49/4
W. Wang, W. Liu J. Huang, Densities and volumetric properties of a (xylene+ dimethyl sulfoxide) at temperature from (293.15 to 353.15) K, J. Chem. Thermodyn., 36 (9) (2004) 743-752.
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2025 Dhirendra Kumar Sharma, Chandra Pal Prajapati, Suneel Kumar
This work is licensed under a Creative Commons Attribution 4.0 International License.
